Oloa

O le lavelave [Cp*Ru(MeCN)3]PF6 o lo'o fa'aalia e fa'apipi'iina le fa'asalaina o le tele o alkynes.Alkynes terminal e mafai ona maua le avanoa i oloa alpha-vinylsilane ma le regioselectivity lelei.O su'esu'ega fa'ailoga a Deuterium o lo'o fa'ailoa mai ai o lo'o galue le fa'agasologa o le fa'aopoopo mama.O le lavelave lava e tasi o loʻo galue i totonu o le alkyne hydrosilylation, lea e faʻamautu ai le filifilia atoatoa mo le faʻagasologa o faʻaopoopoga trans.O le tele o vasega alkyne substrate i totonu, e aofia ai le ava fa'akomepiuta ma le alpha, beta-alkynyl carbonyl compounds, faʻatagaina le faʻavaeina o le vinylsilane regioselective.O le faapalepale o le tele o silanes e mataʻina, e aofia ai alkyl-, aryl-, alkoxy-, ma halosilanes.O lenei tulaga lelei o loʻo faʻaalia i le tuʻufaʻatasiga tuusaʻo o mea faʻapipiʻi triene mo faʻamaʻi faʻapipiʻi intramolecular Diels-Alder cycloadditions.